Respuesta :
Answer. Statement second and third both are correct.
Explanation: When iron(grey) reacts with sulfur(yellow) chemical change takes place in which iron sulfide is formed which black in color.
[tex]Fe(s) + S(s)\rightarrow FeS(s)[/tex]
When we heat copper sulfate-pentahydrate(blue) ,water molecule present in its crystal will get evaporated and it will become an anhydrous copper sulfate which will be white in color.
[tex]CuSO_{4}.5H_{2}O(s)\overset{heat}{\rightarrow} CuSO_{4}(s)+5H_2O(g)[/tex]
So, in both the reactions change in color and change in chemical arrangement has taken place.