A box with a volume of 11.2 L contains 1.0 mol of nitrogen and 2.0 mol of hydrogen at 0°C which of the following statements is true?
R = 8.31 kPa x L/mol x K, PV = nRT

a. The partial pressures of N₂ and H₂ are equal.
b. The partial pressure of N₂ is 202 kPa.
c. The total pressure is 303 kPa.
d. The total pressure in the box is 202 kPa.

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Answer: b. The partial pressure of N₂ is 202 kPa.

Explanation:

According to the ideal gas equation:'

[tex]PV=nRT[/tex]

Pressure of the gas = ?

Volume of the gas = 11.2 L

Temperature of the gas = 0°C = 273K(0°C = 273 K)

Value of gas constant R=8.314 kPaL\Kmol

n = moles of gas = 3.0

[tex]P=\frac{nRT}{V}=\frac{3\times 8.314\times 273}{11.2}=607kPa[/tex]

[tex]p_{N_2}=x_{N_2}\times P[/tex]

[tex]x_{N_2}[/tex] = mole fraction= [tex]\frac{\text {moles of}{N_2}}{\text {total moles}}=\frac{1}{3}=0.33[/tex]

[tex]p_{N_2}=0.33\times 607=202kPa[/tex]

[tex]p_{H_2}=x_{H_2}\times P[/tex]

[tex]x_{H_2}[/tex] = mole fraction= [tex]\frac{\text {moles of}{H_2}}{\text {total moles}}=\frac{2}{3}=0.67[/tex]

[tex]p_{H_2}=0.67\times 607=405kPa[/tex]