How many grams of KCl (s) has been produced from the thermal decomposition of KClO3 (s) that produced 50.0 mL of O2 (g) at 25 degrees C and 1.00 atm pressure.

Respuesta :

Answer:

The mass is [tex]m_{KCl} = 0.102 \ g[/tex]

Explanation:

From the question we are told that

   The volume of oxygen produced is  [tex]V_o = 50mL = 50 *10^{-3} L[/tex]

    The temperature is [tex]T = 25 ^oC = 25* 273 = 298 K[/tex]

     The pressure is  [tex]P = 1.0\ atm[/tex]

From the ideal gas law we have that

      [tex]PV = nRT[/tex]

Where R is the gas constant  with the value

         [tex]R = 0.08206 \ atm \cdot L /mol K[/tex]

  n is the number of moles making it the subject of the formula

          [tex]n = \frac{PV}{RT}[/tex]

Substituting values

          [tex]n = \frac{1 * (50 *10^{-3}) }{0.08206 * 298}[/tex]

          [tex]n = 2.045 *10^{-3} \ mol[/tex]

From the chemical equation

      one mole of  [tex]KClO_3[/tex] produces one mole of  kCl and   [tex]\frac{3}{2}[/tex] of oxygen

       x mole of  [tex]KClO_3[/tex] produces x mole of  kCl and   [tex]2.045 *10^{-3} \ mol[/tex] of oxygen

So    [tex]x = \frac{2.045 *10^{-3}}{\frac{3}{2} }[/tex]

      [tex]x = \frac{2}{3} * 2.045 *10^{-3}[/tex]

      [tex]x = 1.363 *10^{-3} \ mol[/tex]

Now the molar mass of  KCl is a constant with a value

           [tex]M_{KCl} = 74.55 g/mol[/tex]

Now the mass of KCl is mathematically evaluated as

          [tex]m_{KCl} = x * M_{KCl}[/tex]

Substituting values

          [tex]m_{KCl} = 1.363 *10^{-3} * 74.55[/tex]

         [tex]m_{KCl} = 0.102 \ g[/tex]