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At a certain temperature this reaction follows second-order kinetics with a rate constant of Suppose a vessel contains at a concentration of . Calculate the concentration of in the vessel seconds later. You may assume no other reaction is important. Round your answer to significant digits.

Respuesta :

The question is incomplete, here is the complete question:

At a certain temperature this reaction follows second-order kinetics with a rate constant of 14.1 M⁻¹s⁻¹

[tex]2SO_3(g)\rightarrow 2SO_2(g)+O_2(g)[/tex]

Suppose a vessel contains SO₃ at a concentration of 1.44 M. Calculate the concentration of SO₃ in the vessel 0.240 seconds later. You may assume no other reaction is important. Round your answer to 2 significant digits.

Answer: The concentration of [tex]SO_3[/tex] in the vessel after 0.240 seconds is 0.24 M

Explanation:

For the given chemical equation:

[tex]2SO_3(g)\rightarrow 2SO_2(g)+O_2(g)[/tex]

The integrated rate law equation for second order reaction follows:

[tex]k=\frac{1}{t}\left (\frac{1}{[A]}-\frac{1}{[A]_o}\right)[/tex]

where,

k = rate constant = [tex]14.1M^{-1}s^{-1}[/tex]

t = time taken= 0.240 second

[A] = concentration of substance after time 't' = ?

[tex][A]_o[/tex] = Initial concentration = 1.44 M

Putting values in above equation, we get:

[tex]14.1=\frac{1}{0.240}\left (\frac{1}{[A]}-\frac{1}{1.44}\right)[/tex]

[tex][A]=0.245M[/tex]

Hence, the concentration of [tex]SO_3[/tex] in the vessel after 0.240 seconds is 0.24 M