A good confirmatory test for free halogen is: Select one: a. their volatility b. their odor c. their color in water solution d. their color in a non-polar solvent

Respuesta :

d. their color in a non-polar solvent.

Halogens

  • Halogens present in an organic compound forms sodium halide on fusion with sodium metal.
  • Sodium halide extracted with water can be easily identified by adding silver nitrate solution after acidifying with dil. HNO₃.
  • If chlorine is present, a white curdy precipitate soluble in ammonium hydroxide solution is formed.
  • The absence of a precipitate with fluoride ions is unhelpful unless it is known that a halogen is present; otherwise, it indicates that there is no chloride, bromide, or iodide.

Thus, good confirmatory test for free halogens is silver nitrate solution test, which test for color in a non-polar solvent, i.e. option d.

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