When solid sodium hydroxide dissolves in water, the ΔH for the solution process is −44.4 kJ/mol. If a 13.9 g sample of NaOH dissolves in 250.0 g of water in a coffee-cup calorimeter initially at 23.0 °C. What is the final temperature of the solution? Assume that the solution has the same specific heat as liquid water, i.e., 4.18 J/g·K.
a.24.0º C
b.40.2º C
c.37.8º C
d.35.2º C
e.37.0º C

Respuesta :

Answer: The final temperature is 8.13°C

Explanation:

To calculate the number of moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]

Given mass of NaOH = 13.9 g

Molar mass of NaOH = 40 g/mol

Putting values in above equation, we get:

[tex]\text{Moles of NaOH}=\frac{13.9g}{40g/mol}=0.35mol[/tex]

  • To calculate the heat released in the reaction, we use the equation:

[tex]\Delta H_{rxn}=\frac{q}{n}[/tex]

where,

[tex]q[/tex] = amount of heat released

n = number of moles = 0.35 moles

[tex]\Delta H_{rxn}[/tex] = enthalpy change of the reaction = -44.4 kJ/mol

Putting values in above equation, we get:

[tex]-44.4kJ/mol=\frac{q}{0.35mol}\\\\q=(-44.4kJ/mol\times 0.35mol)=-15.54kJ[/tex]

  • To calculate the final temperature, we use the equation:

[tex]q=mc\Delta T=mc(T_2-T_1)[/tex]

where,

q = heat released = -15.54 kJ = -15540 J    (Conversion factor: 1 kJ = 1000 J)

m = mass of water = 250.0 g

c = specific heat capacity of water = 4.18 J/g.K

[tex]T_1[/tex] = initial temperature = [tex]23^oC=[23+273]=296K[/tex]

[tex]T_2[/tex] = final temperature = ?

Putting values in above equation, we get:

[tex]-15540J=250g\times 4.18J/g.K\times (T_2-296)\\\\T_2=281.13K[/tex]

Converting the temperature from kelvins to degree Celsius, by using the conversion factor:

[tex]T(K)=T(^oC)+273[/tex]

[tex]281.13=T(^oC)+273\\T(^oC)=8.13^oC[/tex]

Hence, the final temperature is 8.13°C