Respuesta :

Answer:

-2.79°C is the expected freezing point of a 0.50 m solution of lithium sulfate.

Explanation:

Freezing point of water = T =0°C

Melting point of sample = [tex]T_f[/tex]

Depression in freezing point = [tex]\Delta T_f[/tex]

Depression in freezing point  is also given by formula:

[tex]\Delta T_f=i\times K_f\times m[/tex]

[tex]K_f[/tex] = The freezing point depression constant

m = molality of the sample

i = van't Hoff factor  

We have: [tex]K_f[/tex] = 40°C kg/mol

m = 0.50 m

i = 3 (lithium sulfate is an ionic compound)

[tex]\Delta T_f=3\times 1.86^oC kg/mol\times 0.50 m=2.79^oC[/tex]

[tex]\Delta T_f=T- T_f[/tex]

[tex]T_f=T-\Delta T_f=0^oC-2.79^oC=-2.79^oC[/tex]

-2.79°C is the expected freezing point of a 0.50 m solution of lithium sulfate.

The freezing point of the solution is - 2.79∘c.

Using the formula;

ΔT = K m i

ΔT = freezing point depression

K = Freezing point constant

m = molality of solution

i = Van't Hoff factor

From the question;

K =  1.86 ∘c/m

m = 0.50 m

i = 3

ΔT = 1.86 ∘c/m × 0.50 m × 3

ΔT = 2.79∘c

But ΔT = Freezing point of pure solvent - freezing point of solution

Freezing point of pure solvent = 0∘c

Freezing point of solution = Freezing point of pure solvent - ΔT

Freezing point of solution = 0∘c - 2.79∘c

Freezing point of solution = - 2.79∘c

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